Molecular magnets
- Among all C-, N-, and O-centered polyradicals, high-spin nitrenes possess the largest magnetic anisotropy and are of considerable interest as multi-level molecular spin systems for exploration of organic molecular magnetism and quantum information processing. Although the first representatives of quintet and septet nitrenes were obtained almost 50 years ago, the experimental and theoretical studies of these highly reactive species became possible only recently, owing to new achievements in molecular spectroscopy and computational chemistry. Meanwhile, dozens of various quintet dinitrenes and septet trinitrenes were successfully characterized by IR, UV/Vis, and EPR spectroscopy, thus providing important information about the electronic structure, magnetic properties and reactivity of these compounds.
| Author: | Sergei V. ChapyshevORCiDGND, Enrique Méndez-VegaORCiDGND, Wolfram SanderORCiDGND |
|---|---|
| URN: | urn:nbn:de:hbz:294-109602 |
| DOI: | https://doi.org/10.1002/chem.202002234 |
| Parent Title (English): | Chemistry - A European journal |
| Subtitle (English): | The synthesis and characterization of high-spin nitrenes |
| Publisher: | Wiley |
| Place of publication: | Weinheim |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2024/02/29 |
| Date of first Publication: | 2020/06/24 |
| Publishing Institution: | Ruhr-Universität Bochum, Universitätsbibliothek |
| Tag: | EPR spectroscopy; magnetism; matrix isolation; nitrenes; radicals |
| Volume: | 27 |
| Issue: | 4 |
| First Page: | 1258 |
| Last Page: | 1269 |
| Note: | Dieser Beitrag ist auf Grund des DEAL-Wiley-Vertrages frei zugänglich. |
| Institutes/Facilities: | Lehrstuhl für Organische Chemie II |
| Dewey Decimal Classification: | Naturwissenschaften und Mathematik / Chemie, Kristallographie, Mineralogie |
| open_access (DINI-Set): | open_access |
| faculties: | Fakultät für Chemie und Biochemie |
| Licence (English): |  Creative Commons - CC BY-NC-ND 4.0 - Attribution-NonCommercial-NoDerivatives 4.0 International |
