Insight into the X-ray absorption spectra of Cu-porphyrazines from electronic structure theory

  • Transition metal porphyrazines are a widely used class of compounds with applications in catalysis, organic solar cells, photodynamic therapy, and nonlinear optics. The most prominent members of that family of compounds are metallophtalocyanines, which have been the subject of numerous spectroscopic and theoretical studies. In this work, the electronic structure and X-ray absorption characteristics of three Cu-porphyrazine derivatives are investigated by means of modern electronic structure theory. More precisely, the experimentally observed N K-edge and Cu L-edge features are presented and reproduced by time-dependent density functional theory, restricted open-shell configuration interaction, and a restricted active space approach. Where possible, the calculations are used to interpret the observed spectroscopic features in terms of electronic transitions and, furthermore, to connect spectral differences to chemical variations. Part of the discussion of the computational results concerns the impact of various parameters and approximations that are used for the calculations, for example, the choice of active space.

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Author:Esma Birsen BoydasGND, Bernd WinterGND, David BatchelorORCiDGND, Michael RömeltORCiDGND
Parent Title (English):International journal of quantum chemistry
Place of publication:Weinheim
Document Type:Article
Date of Publication (online):2024/02/23
Date of first Publication:2020/10/26
Publishing Institution:Ruhr-Universität Bochum, Universitätsbibliothek
Tag:electronic structure theory; transition metal chemistry; x-ray absorption spectroscopy
Issue:3, Artikel e26515
First Page:e26515-1
Last Page:e26515-13
Dieser Beitrag ist auf Grund des DEAL-Wiley-Vertrages frei zugänglich.
Institutes/Facilities:Lehrstuhl für Theoretische Chemie
Dewey Decimal Classification:Naturwissenschaften und Mathematik / Chemie, Kristallographie, Mineralogie
open_access (DINI-Set):open_access
faculties:Fakultät für Chemie und Biochemie
Licence (English):License LogoCreative Commons - CC BY-NC-ND 4.0 - Attribution-NonCommercial-NoDerivatives 4.0 International