Thermoregeneration of plastrons on superhydrophobic coatings for sustained antifouling properties

  • A popular and desirable function of superhydrophobic coatings is their remarkable ability to retain an entrapped layer of air, called a plastron, when submerged underwater. The drawback is that the air layer is short‐lived due to solvation into the surrounding liquid. While manipulating the solubility of gases using temperature is a possible approach, it generally requires inefficiently heating large volumes of water. Following the demonstrated ability to maintain air bubbles on superhydrophobic surfaces for drag reduction, this article introduces a novel method of extracting gas from water to replenish and stabilize the plastron on superhydrophobic surfaces for sustained antifouling abilities. This method involves locally heating the liquid surrounding a superhydrophobic coating, reducing gas solubility, and causing the gas to nucleate at the liquid–air interface. The approach requires a relatively low energy input, due to the small volume of locally heated water. With a constant supply of equilibrated water and minimal energy input, the plastron can survive indefinitely without the need for a mechanical delivery of air. The thermoregenerating superhydrophobic samples were shown to exhibit excellent antifouling behavior and inhibited diatom attachment over a period of 5 days.

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Metadaten
Author:Tomer SimovichORCiDGND, Axel RosenhahnORCiDGND, Robert N. LambGND
URN:urn:nbn:de:hbz:294-79672
DOI:https://doi.org/10.1002/adem.201900806
Parent Title (English):Advanced engineering materials
Publisher:Wiley-VCH Verlag
Place of publication:Weinheim
Document Type:Article
Language:English
Date of Publication (online):2021/03/19
Date of first Publication:2019/10/18
Publishing Institution:Ruhr-Universität Bochum, Universitätsbibliothek
Tag:air layers; antifouling; gas solubilities; superhydrophobic
Volume:22
Issue:3, Artikel 1900806
First Page:1900806-1
Last Page:1900806-6
Note:
Dieser Beitrag ist auf Grund des DEAL-Wiley-Vertrages frei zugänglich.
Institutes/Facilities:Lehrstuhl für Analytische Chemie und Zentrum für Elektrochemie, Biointerfaces
Dewey Decimal Classification:Naturwissenschaften und Mathematik / Chemie, Kristallographie, Mineralogie
open_access (DINI-Set):open_access
faculties:Fakultät für Chemie und Biochemie
Licence (English):License LogoCreative Commons - CC BY-NC 4.0 - Attribution-NonCommercial 4.0 International