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Peter Haußmann, Joachim Melbert

• A new impedance spectroscopy measurement procedure for automotive battery cells is presented, which is based on waveform shaping. The method is optimized towards a short measurement duration, high excitation power and increased frequency resolution and overcomes limitations of established methods. For a given spectral magnitude profile, a corresponding time domain waveform is derived from the inverse discrete Fourier transform. Applying an identical initial phase angle for each frequency component, the resulting signal exhibits a high peak-to-peak amplitude at relatively low total excitation power. This limits the maximum allowed power for quasi-linear excitation. Altering the phase angles randomly spreads the excitation power across the complete measurement duration. Thereby, linearity is preserved at higher excitation power. A large set of phase patterns is evaluated statistically in order to obtain a phase pattern with a significant peak-to-peak amplitude decrease. By means of numerical optimization, even further peak-to-peak amplitude reduction is achieved. Including window functions in the synthesis concept minimizes spectral leakage without compromising the spectral signal magnitude in the frequency range of interest. A time domain waveform optimized for impedance spectroscopy on lithium ion cells is synthesized based on the proposed approach and evaluated on real automotive cells. The resulting impedance data show good concordance with established standard measurement procedures at significantly reduced measurement duration and charge throughput. Additionally, increased frequency resolution is achieved, enhancing the level of detail of the obtained impedance data. The method is used for improved localization of aging effects in the cells, without further stress of the cells by the measurement procedure.